Visual Studio 2010 and .NET Framework 4 Training Kit

http://www.microsoft.com/downloads/details.aspx?FamilyID=752CB725-969B-4732-A383-ED5740F02E93&displaylang=en

Learn about:

• C# 4
• Visual Basic 10
• F#
• Parallel Extensions
• Windows Communication Foundation
• Windows Workflow
• Windows Presentation Foundation
• ASP.NET 4
• Windows 7
• Entity Framework
• ADO.NET Data Services
• Managed Extensibility Framework
• Visual Studio Team System

Channel 9: http://channel9.msdn.com/learn/courses/VS2010/